Understanding value creation in closed loop supply chains – Past findings and future directions

The topic of value creation through the recovery of returned products in closed loop supply chains is scattered across various bodies of literature. We undertake a systematic literature review of 144 articles in relevant green, reverse and closed loop supply chain literature to synchronize existing knowledge on value creation. Value manifestations of four types of value, namely economic, environmental, information and customer value, are identified. Value adding concepts from the forward- and reverse supply chain may leverage the process of value creation. They are classified into six subclasses, namely partnerships and collaboration, product design characteristics, service concepts, IT solutions, supply chain processes and organizational characteristics. We present a conceptual framework on a strategic level. In this way companies can create competitive advantages by closing the loop. The results of the literature analysis suggest avenues for future research on the operational and strategic level.     

Emissions from distributed vs. centralized generation: The importance of system performance

Distributed generation (DG) offers a number of potential benefits, but questions remain about environmental performance. Air emissions from five key DG technologies; gas engines, diesel engines, gas turbines, micro-turbines, and fuel cells, were systematically compared with total energy supply systems based on centralized gas turbines (CCGT) and coal steam turbines plus distributed heating (DH) using gas-fired boilers. Based on emissions and operational factors from existing commercially marketed DG-CHP technologies, combined heat and power (CHP) applications are considered, which are remotely monitored and operated as base-load supply. Emissions results are characterized using heat-to-power ratios (HPRs), which concisely describe different types of energy demand under different applications or seasonal conditions. At an HPR of zero (i.e. the special case of electricity-only), CCGT with DH gives the lowest emissions portfolio, but at HPR values typical for buildings in the United States, efficiency advantages ensure gas-fired combustion DG-CHP technologies become broadly competitive across the range of key emissions. Fuel cell DG-CHP provides a very low emissions portfolio, but at a significant cost premium. At higher HPR values, emissions from heat supply can become a key issue, leading to the surprising finding that some combustion-based DG-CHP systems have lower total emissions than fuel cell-based systems. Based on these insights, the paper concludes with a discussion of streamlined yet rigorous regulatory approaches for DG-CHP technologies.     

Passive location of the nonlinear systems with fuzzy uncertainty

With the merits such as hiding receiving, easy-deploying and high security, passive location has attracted more and more attention and plays an important role in fields as diverse as navigation, location, and tracking, etc. However, the current filters models for passive location methods are most under the framework of the probability theory, thus they can not estimate the state in some passive location with fuzzy uncertainty accurately. Although the fuzzy extended Kalman filter (FEKF) can deal with the fuzzy uncertainty, it unavoidably introduces truncation error. In this paper, based on the FEKF and the iterated extended Kalman filter (IEKF) principle, a new fuzzy passive location model is built, and moreover, an iterated fuzzy extended Kalman filter (IFEKF) is proposed for estimating the target state. Compared to the FEKF and the IEKF, the proposed algorithm can not only reduce the truncation error, but also deal with fuzzy uncertainty. Moreover, it is proved that the IFEKF update is an application of the Gauss–Newton method. Then, a fuzzy passive location algorithm is proposed. Simulation results demonstrate that the proposed approach has better estimation precision than the traditional fuzzy extended Kalman filter.     

Influence of heat treatments and anodization on fatigue life of 2017A alloy

In order to investigate the coupled effects of heat treatments and anodizing processes on fatigue life of aluminium alloy 2017A, a series of fatigue tests were conducted at 25 Hz. The effect of different tempers, naturally and artificially ageing (T4 and T6) and overageing (T7) conditions before sulphuric anodization were studied. Additionally, information on the microstructure of the anodic films was acquired by Scanning Electron Microscopy (SEM) analyses. The image analysis yielded qualitative information on the evolution of the surface morphology as a function of the substrate microstructure. Hence measured mechanical properties were directly related to the corresponding microstructure, the result of fatigue tests showed a decrease in fatigue life of anodized specimens as compared to untreated ones. This phenomenon became more pronounced in the T6 and T7 states. The decrease in the fatigue life could mainly be attributed to the brittle nature of oxide layer and to the heterogeneous microstructure of the film.     

Dynamic mechanical analysis of the multiple glass transitions of plasticized wheat gluten biopolymer

Glass transition of thermo‐molded biomaterials made from wheat gluten and its main protein classes is studied by dynamic mechanical analysis (DMA). The materials are plasticized with variable contents of glycerol (30–40 wt %) and water (0–20 wt %). For all materials, three successive relaxation phases are systematically detected. Their positions shift to lower temperature as the plasticizer content of materials increases. Composition in gluten, glycerol and water of each relaxation phase is estimated using the Couchman‐Karasz model. Irrespective of the plasticizer content or composition, the relaxation phases shows rather constant plasticizer volume fractions. The low‐, middle‐, and high relaxation phases include respectively around 30, 60 and 80 vol % of gluten protein. These relaxations are assigned to the segmental motion of the surface amino‐acid side groups, to the collective motion of packed gluten proteins, and to the gain in protein conformational mobility as a 2D network of interacting plasticizer molecules forms. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43254.     

Nanocomposites of PBAT and cellulose nanocrystals modified by in situ polymerization and melt extrusion

Cellulose nanocrystals (CNC) were successfully grafted with a low molecular weight poly(butylene glutarate) through an in situ polymerization procedure. The grafting treatment decreased the CNC hydrophilic character and increased the onset of their thermal degradation by approximately 20°C, thus increasing the possibilities of CNC application. Composites of grafted and nongrafted CNC with a poly(butylene‐adipate‐co‐terephthalate) (PBAT) matrix were prepared by melt extrusion. The CNC addition led to an increase of 50% of the tensile elastic modulus of the PBAT. In addition, dynamic mechanical thermal analysis showed that the composite with CNC retained its high modulus even at temperatures far above the glass transition temperature of PBAT. At 60°C the storage modulus of the composite with CNC was approximately 200% higher than that of the pure PBAT. Thus, in this work, nanocomposites of improved properties were obtained through a combination of in situ polymerization and melt extrusion. POLYM. ENG. SCI., 56:1339–1348, 2016. © 2016 Society of Plastics Engineers     

Mechanical and barrier properties of cardboard and 3D packaging coated with microfibrillated cellulose

Microfibrillated cellulose (MFC) is increasingly used with cellulosic substrates and especially with paper materials. Its use with cardboard remains not reported and the study of mechanical and barrier properties of MFC‐coated cardboard has been investigated in this article. The influence of coating process as well as the effect of MFC have been highlighted by comparing different MFC‐coated cardboard samples with PE‐coated cardboard samples. MFC was coated using bar coating process. Their distribution and homogeneity onto cardboard was observed using techniques such as SEM and FE‐SEM. Tests such as oxygen and air permeability, bending stiffness, and compressive strength have been carried out. The coating process used impacts significantly cardboard properties by two opposite ways: on one hand it damages the structure cohesion of cardboard decreasing its compressive strength; on the other hand it increases its bending stiffness by increasing considerably the samples thickness. The addition of MFC counterbalances the negative effects of the coating process: bending stiffness and compressive strength are indeed improved by 30% in machine direction. On the contrary, MFC does not enhance much cardboard barrier properties, although it considerably increases their water absorption. Within a framework of packaging application, MFC will rather have consequent effects on cardboard's properties as blend or as part of the multilayer structure. Other applications have to be considered for its use as top layer. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40106.     

Light scattering and extinction in polydisperse systems

A simple approach to predict transmittance spectra of polydisperse systems is recalled and applied to various model systems (spinel-like particles in water, pores in a spinel-like matrix) and real systems (spinel in water, diamond in water, amorphous carbon soot in isopropanol) in order to investigate principal effects of size distributions (normal/lognormal, narrow/wide, monomodal/bimodal, shift of mode positions, shift of mode heights) and optical properties (refractive index contrast, with or without absorption) on the in-line transmittance. A comparison of predicted and measured spectra showed that size distributions with more small particles cause a more significant decrease in transmittance (at least for sufficiently short wavelengths) and that laser diffraction may seriously underestimate the amount of small particles (for absorbing particles, for which the influence on transmittance is enormous, a difference of up to 30% in absolute transmittance measured via spectrophotometry has been found against predictions based on laser diffraction results).     

Estimating dynamic power consumption for memristor-based CiM architecture

Nowadays, Computing-in-Memory (CiM) represents one of the most relevant solutions to deal with CMOS technological issues and several works have been proposed so far targeting front and back-end synthesis. However, a given CiM architecture can be synthesized depending on different parameters, leading to different implementations w.r.t. area, power consumption and performance. It is thus mandatory to have an evaluation framework to characterize the actual implementation depending on the above terms. This is even more important during the Design Exploration phase, in which many different implementations are explored to identify the best candidate w.r.t. the user requirements. In this work, we focus on the dynamic power consumption estimation of a given CiM implementation. Instead of resorting to a simulation-based power estimation, we propose an analytical approach that will dramatically speed up the estimation since no simulations are required. By comparing the proposed approach against the simulation-based method over a massive experimental campaign, we show that the accuracy of the estimation turns out to be very high.     

Nanocellulose-based films and their emerging applications

Extensive research has been directed towards the reinvention of paper for advanced applications. Nanocellulose-based films, a novel class of specialty paper primarily made of nanocellulose, demonstrate an ideal combination of sustainability and enhanced or novel properties. Enormous efforts have been devoted to enhancing these intrinsic properties and/or creating novel functions to expedite and expand the use of these materials in high-end fields such as touchscreen, solar cells, and nanogenerators. We review state-of-the-art advances in nanocellulose-based films and their utilization in several emerging and promising fields. We begin with an introduction of four types of nanocellulose-based films distinguished by their functional material loads (e.g., synthetic macromolecular polymers, 0D, 1D, and 2D nanomaterials), which involves their manufacturing techniques, structure design, properties, novel functions, and underlying principles. Additionally, we summarize the value-added applications of nanocellulose-based films in flexible electronics, energy converting or harvesting devices, and water treatment. Finally, we provide a critical viewpoint on the remaining challenges and future opportunities in this field.